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The copolymer has the alternating structure I irrespective of the comonomer feed composition. Moderate alternating behavior occurs when either (1) both r1 and r2 are small (r1 r2 very small, close to 0) or (2) one r value is small and the other r is zero (r1 r2 0). The copolymer composition tends toward alternation but is not the perfectly alternating structure I . The behavior of most comonomer systems lies between the two extremes of ideal and alternating copolymerization. As the r1 r2 product decreases from one toward zero, there is an increasing tendency toward alternation. Perfect alternation occurs when r1 and r2 are both zero. The tendency toward alternation and the tendency away from ideal behavior increases as r1 and r2 become progressivley less than unity. The range of behaviors can be seen by considering the situation where r2 remains constant at 0.5 and r1 varies between 2 and 0. Figure 6-2 shows the copolymer composition as a function of the feed composition in these cases. The curve for r1 2 shows the ideal type of behavior described previously. As r1 decreases below 2, there is an increasing tendency toward the alternating behavior with each type of propagating species preferring to add the other monomer. The increasing

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Fig. 6-2 Dependence of the instantaneous copolymer composition F1 on the initial comonomer feed composition f1 for the indicated values of r1 , where r2 is constant at 0.5. After Walling [1957] (by permission of Wiley, New York) from plot in Mayo and Walling [1950] (by permission of American Chemical Society, Washington, DC).

Pass the cable through the grommet in the original instrument s case so that the stillinsulated main cable just passes through A nylon wire tie pulled tightly around the wire, just inside the case, will keep the cable from slipping out (see Figure 11-5)..

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